HIx 용액을 이용한 분젠 반응에서 상 분리 조성에 미치는 SO2-O2 혼합물 기체의 영향
공학 > 화학공학
한상진 ( Sang Jin Han ) , 김효섭 ( Hyo Sub Kim ) , 안병태 ( Byung Tae Ahn ) , 김영호 ( Young Ho Kim ) , 박주식 ( Chu Sik Park ) , 배기광 ( Ki Kwang Bae ) , 이종규 ( Jong Gyu Lee )
한국수소및신에너지학회(구 한국수소에너지학회)
한국수소 및 신에너지학회논문집 2012년, 제23권 제5호, 421~428페이지(총8페이지)
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    The Sulfur-Iodine (SI) thermochemical hydrogen production process is one of the most promising thermochemical water splitting technologies. In the integrated operation of the SI process, the O2 produced from a H2SO4 decomposition section could be supplied directly to the Bunsen reaction section without preliminary separation. A HIx (I2+HI+H2O) solution could be also provided as the reactants in a Bunsen reaction section, since the sole separation of I2 in a HIx solution recycled from a HI decomposition section was very difficult. Therefore, the Bunsen reaction using SO2-O2 mixture gases in the presence of the HIx solution was carried out to identify the effect of O2. The amount of I2 unreacted under the feed of SO2-O2 mixture gases was little higher than that under the feed of SO2 gas only, and the amount of HI produced was relatively decreased. The O2 in SO2-O2 mixture gases also played a role to decrease the amount of a impurity in HIx phase by only striping effect, while that in H2SO4 phase was hardly affected.
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