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분야 : 자연과학 > 과학교육
발행기관 : 경북대학교 과학교육연구소
간행물정보 : 과학교육연구지, 2002 pp.149~162 (총 14pages)
 
 
영문초록
[1.1.1]Paddlane has an inverted structure at two bridge-head carbon atoms. We will describe the reaction of [1.1.1]Propellane and [1.1.1.1]Paddlane. The reaction of [1.1.1]propellane with singlet methylene affored 1.3-Dimethylene as the major product and [1.1.1.1]paddlane as the minor products were obtained. The reaction of [1.1.1]propellane with triplet methylene was carried out in the similar condition. The result afforded 1,3-Dimethylenecylopropane as the major product and various side products were also obtained. But no trace of [1.1.1.1]paddlane was detected. After the synthesis of [1.1.1.1]paddlane, continuously [1.1.1.1]paddlane reacts with iodide. The product that I expected for 1.3-diiodo-tricyclo[1.1.1.1]hexane is different, and has unsymmetrical structure.
 
 
[1.1.1.1]Paddlane
 
다운로드 1v100180.pdf