by lithium ion intercalation
Si has theoretical capacity of 4200mAh/g
Due to it’s large volume change, pulverization can be occurred.
Silicon has high-capacity but poor cycle stability
Carbon has low-capacity but good cycle stability
So silicon/carbon composites can have higher capacity than single carbon anode,
and better cycle stability than single silicon anode.
etching
SiO2
N-type
Si
N-type
SiO2
⦁SiO2 that does not have PR is removed by wet etching and also remaining PR is removed by acetone.
Source Drain Opening
○ SiO2 Deposition ( 100nm ) ○ PR(positive) Coating
SiO2
SiO2
N-type
Si
N-type
SiO2
⇒
PR
SiO2
SiO2
N-type
Si
N-type
SiO2
To prevent silicon from agglomerating
→ should cool the solid quickly
Rapid cooling
→ large thermal gradient in crystal
Postulate K=20W/m K
Diameter of wafer: 10-20 cm
L (latent heat of fusion) = 340 cal/g
Temperature gradient in silicon CZ (dT/dx) : 100°C/cm
1. Li / S battery
현재 차세대 이차전지에 대한 관심이 집중되면서 2차전지의 한계로 지적되던 에너지 밀도 상승의 한계, 안정성에 대한 불안감, 그리고 높은 원가 부담을 개선하기 위한 새로운 형태의 전지가 등장함은 물론 과거에 소개되었던 개념까지 재조명 받고 있다. 풍부한 자원인 황을 활용하여